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Tuning Cooperative Interactions in Redox-Active Metal-Organic Frameworks for Gas Adsorption
- Oktawiec, Julia
- Advisor(s): Long, Jeffrey R
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Abstract
The discovery of permanent porosity in metal–organic frameworks has ushered in many developments towards the application of these materials for gas separations and storage. The work in this dissertation describes efforts to design and target redox-active metal–organic frameworks for gas separations and storage, such as O2 adsorption, O2/N2 separations, and NO adsorption. The usage of structural characterization, in particular by powder X-ray diffraction, to better understand adsorption in metal–organic frameworks is highlighted.